Includes bibliographical references and index.

Online resource; title from PDF title page (EBSCO, viewed December 12, 2014).

Best Synthetic Methods: ORGANOPHOSPHORUS (V) CHEMISTRY provides systematic coverage of the most common classes of pentavalent organophosphorus compounds and reagents (including phosphonyl, phosphoryl, and organophosphates), and allows researchers an easy point of entry into this complex and economically important field. The book follows the Best Synthetic Methods format, containing practical methods, synthetic tips, and shortcuts. Where relevant, articles include toxicity data and historical context for the reactions. Typical analytical and spectroscopic data are also presented to enable scientists to identify key compound characteristics. The book is a valuable companion to research chemists in both academia and industry, summarizing the best practical methods (often originating in difficult-to-access, foreign-language primary literature) in one place. It is ideally suited for those working on industrial applications of these compounds, including insecticides, herbicides, flame retardants, and plasticizers.

Front Cover; Best Synthetic Methods; OTHER VOLUMES IN THE SERIES; Best Synthetic Methods; Copyright; ACKNOWLEDGEMENTS; REFERENCES; 1.4 PHOSPHORUS COMPOUNDS IN LIVING SYSTEMS; 1.5.3 ORGANOPHOSPHORUS PESTICIDES; 1.6 NOMENCLATURE OF ORGANOPHOSPHORUS COMPOUNDS; 1.7 CHIRAL PHOSPHORUS COMPOUNDS AND BIOLOGICAL IMPLICATIONS; 1.8 PHOSPHORUS-CONTAINING PHARMACEUTICALS; 1.9 FIRE RETARDANTS AND FIRE-EXTINGUISHING COMPOUNDS; 1.10 TOXICOLOGY AND MEDICAL TREATMENT OF ORGANOPHOSPHORUS COMPOUNDS; 1.11 FLUOROGENIC NERVE AGENT MIMICS FOR SCREENING FOR IMPROVED BIOSCAVENGERS.

880-01 2.23 s-alkyl alkylphosphonochloridothiolates r(r2)p(o)cl2.24 alkyl alkylphosphonofluoridates r(r2)p(o)f; 2.25 n-alkyl or n, n-dialkyl alkylphosphonamidofluoridates r(r2 n)p(o)f (x=h or r2 ; 2.26 s-alkyl alkylphosphonofluoridothiolates r(r2)p(o)f; 2.27 alkyl alkylphosphonocyanidates r(r2)p(o)cn; 2.28 alkyl alkylphosphonic acids r(r2)p(o)oh; 2.29 alkylphosphonofluoridic anhydrides r(f)p(o)op(o)(f)r; 2.30 dialkyl dialkylpyrophosphonates r(r2)p(o)op(o)(or2 r; 2.31 n, n-dialkyl-p-alkylphosphonamidic anhydrides r(r2 n)p(o)op(o)(nr2)r.

2.32 s, s2 dialkyl dialkyldithiopyrophosphonates r(r2)p(o)op(o)(sr2 r2.33 o-alkyl n-alkyl alkylphosphonamidates rp(o)(nr2)or; 2.34 bis(n, n-dialkyl) alkylphosphonodiamidates rp(o)(nr2)2; 2.35 o, s-dialkyl alkylphosphonothiolates rp(o)(or)sr; 2.36 s-alkyl n-alkyl (or n, n-dialkyl) alkylphosphonamidothiolates rp(o)(nr2)sr; 2.37 s, s2 dialkyl alkylphosphonodithiolates rp(o)(sr2)2; references; 3.9 s-alkyl alkylphosphonochloridothiolothionates rs(r2 p(s)cl; 3.13 alkyl alkyl/aryl alkylphosphonothionates ro(r2 p(s)or2 ; 4.9 alkyl phosphorodiisothiocyanatidates rop(o)(ncs)2.

4.35 trialkyl phosphates (ro)2p(o)or4.39 dialkyl enolphosphates (ro)2p(o)ocrcr2 (perkow reaction); 4.40 dialkyl phosphorazidates (ro)2p(o)n3; 4.41 dialkyl phosphoramidates (ro)2p(o)nr2 (todd-atherton reaction); 4.42 dialkyl n-arylphosphoramidates (ro)2p(o)nhar; 4.43 diaryl phosphoramidates (aro)2p(o)nr2; 4.44 dialkyl n-methyl-n-(phosphoryl)phosphoramidates (ro)2p(o)n(me)p(x)r2; 4.45 dialkyl n-methyl-n-acylphosphoramidates (ro)2p(o)n(me)cor2 4.46 disubstituted n-aryl(or alkyl)-n-chlorophosphoramidates (ro)2p(o)n(cl)ar; 4.47 dialkyl n, n-dihalophosphoramidates (ro)2p(o)nx2 (x=cl or br).