000			05859cam a2200721Ii 4500
001			ocn861559351
003			OCoLC
005			20171105120129.0
006			m o d
007			cr |||||||||||
008			131026s2014 gw a ob 001 0 eng d
016	7		_a016449660 _2Uk
020			_a9783527658855 _q(electronic bk.)
020			_a3527658858 _q(electronic bk.)
020			_z9783527658824
020			_z3527658823
020			_z9783527658848
020			_z352765884X
020			_z9783527658831
020			_z3527658831
020			_z9783527332946
020			_a3527332944
020			_a9783527332946
020			_a9781306028875
020			_a1306028876
029	1		_aAU@ _b000052334853
029	1		_aCHBIS _b010131762
029	1		_aCHVBK _b314709541
029	1		_aNZ1 _b15340121
029	1		_aDEBSZ _b431544077
035			_a(OCoLC)861559351 _z(OCoLC)867078944 _z(OCoLC)891395987 _z(OCoLC)961543277 _z(OCoLC)962557665
037			_a534138 _bMIL
040			_aEBLCP _beng _erda _epn _cEBLCP _dIDEBK _dCUS _dOCLCQ _dN$T _dUKMGB _dYDXCP _dUKDOC _dIUL _dOCLCF _dOCLCQ _dE7B _dDEBSZ _dCOO _dCDX _dRECBK _dOCLCQ
049			_aMAIN
050		4	_aQD471
072		7	_aSCI _x013050 _2bisacsh
082	0	4	_a541.7
100	1		_aAntonov, Liudmil, _eeditor.
245	1	0	_aTautomerism : methods and theories / _cedited by Liudmil Antonov. _h[electronic resource]
260			_aWeinheim, Germany : _bWiley-VCH, _c[2014]
300			_a1 online resource (xx, 377 pages) : _billustrations
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
500			_a3.5.2 Reaction Path Calculations and Energy Barriers for Proton Transfer.
504			_aIncludes bibliographical references (pages 395-403) and index.
505	0		_aTautomerism; Contents; Preface; List of Contributors; 1 Tautomerism: Introduction, History, and Recent Developments in Experimental and Theoretical Methods; 1.1 The Definition and Scope of Tautomerism: Principles and Practicalities; 1.2 Causes of Reversal in Tautomeric Form: Aromatic Resonance; 1.3 Causes of Reversal in Tautomeric Form: Lone-Pair and Dipolar Repulsion; 1.4 Causes of Reversal in Tautomeric Form: Selective Stabilization Through ""Far"" Intramolecular Hydrogen Bonding; 1.5 Changes in Tautomeric Form Brought About by Electronegative Substituents.
505	8		_a1.6 The Influence of Solvent on Tautomeric Form; 1.7 Tautomeric Equilibrium: Historical Overview of an Analytical Problem; 1.8 Short Historical Overview of Tautomerization Dynamics; 1.9 Conclusions and Outlook; References; 2 Absorption UV-vis Spectroscopy and Chemometrics: From Qualitative Conclusions to Quantitative Analysis; 2.1 Introduction; 2.2 Quantitative Analysis of Tautomeric Equilibria; 2.2.1 Classical Spectrophotometric Analysis, Limitations, and Early Attempts to Find a Solution; 2.2.2 Quantitative Analysis by Using Bands Decomposition.
505	8		_a2.2.3 Change in the Environment Affects the Equilibrium: Physical Meaning and Mathematical Expression; 2.3 Analysis of Real Tautomeric Systems; 2.3.1 Keto-Enol Tautomerism in 4-(phenyldiazenyl)naphthalen-1-ol: Solvent Effect; 2.3.2 Keto-Enol Tautomerism in 1-((phenylimino)methyl)naphthalen-2-ol: Verification of the Approach; 2.3.3 Keto-Enol Tautomerism in 1-(phenyldiazenyl)naphthalen-2-ol and 1-((phenylimino)methyl)naphthalen-2-ol: Effects of the Temperature and the Strength of Intramolecular Hydrogen Bonding.
505	8		_a2.3.4 Ammonium-Azonium Tautomerism in 4-((4-aminophenyl)diazenyl)-N, N-dimethylaniline: Effect of Protonation and Solvent; 2.4 Concluding Remarks; References; 3 Studies of Photoinduced NH Tautomerism by Stationary and Time-Resolved Fluorescence Techniques; 3.1 Introduction; 3.2 Photoinduced Proton/Hydrogen Atom Transfer; 3.2.1 Direct Intramolecular Proton Transfer Reactions; 3.2.2 Solvent-Mediated NH Tautomerism; 3.3 Fluorescence Techniques for Studying Tautomerism; 3.3.1 Steady-State Fluorescence Methods; 3.3.2 Time-Resolved Fluorescence Approaches.
505	8		_a3.3.3 Advanced Techniques in Fluorescence Spectroscopy; 3.3.3.1 Fluorescence Anisotropy; 3.3.3.2 Fluorescence Microscopy and Fluorescence Correlation Spectroscopy; 3.4 Tautomerism in Bifunctional NH/N Azaaromatics; 3.4.1 Intramolecular NH/N Tautomerization; 3.4.2 Intermolecular NH/N Tautomerization in Hydrogen-Bonded Dimers; 3.4.3 Tautomerization in Solute-Solvent Hydrogen-Bonded Complexes; 3.5 Ab initio and DFT Computational Methods; 3.5.1 Reaction Mechanisms and Cooperativity in Proton Migrations; 3.5.1.1 Concerted versus Stepwise Mechanism.
520			_a"Covering the gap between basic textbooks and over-specialized scientific publications, this is the first reference available to describe this interdisciplinary topic for PhD students and scientists starting in the field. The result is an introductory description providing suitable practical examples of the basic methods used to study tautomeric processes, as well as the theories describing the tautomerism and proton transfer phenomena. It also includes different spectroscopic methods for examining tautomerism, such as UV-VIs, time-resolved fluorescence spectroscopy, and NMR spectroscopy."--Publisher's website.
588	0		_aOnline resource; title from PDF title page (Wiley, viewed November 12, 2013).
650		0	_aTautomerism.
650		7	_aSCIENCE _xChemistry _xPhysical & Theoretical. _2bisacsh
650		7	_aTautomerism. _2fast _0(OCoLC)fst01143591
650		7	_aScience. _2ukslc
655		4	_aElectronic books.
655		0	_aElectronic books.
776	0	8	_iPrint version: _aAntonov, Liudmil. _tTautomerism : Methods and Theories. _dHoboken, N.J. : Wiley, ©2013 _z9783527332946 _w(OCoLC)852808613
856	4	0	_uhttp://onlinelibrary.wiley.com/book/10.1002/9783527658824 _zWiley Online Library
942			_2ddc _cBK
999			_c207050 _d207050