000			03979cam a2200421Ki 4500
001			ocn870333919
003			OCoLC
005			20190328114807.0
006			m o d
007			cr cnu---unuuu
008			140212s2014 mau o 000 0 eng d
040			_aOPELS _beng _erda _epn _cOPELS _dE7B _dCDX _dOCLCF _dOCLCQ _dU3W _dD6H _dAU@
020			_a9780124170346 _q(electronic bk.)
020			_a012417034X _q(electronic bk.)
035			_a(OCoLC)870333919
050		4	_aQD262
082	0	4	_a547.2 _223
100	1		_aRoos, Gregory, _eauthor.
245	1	0	_aKey chiral auxiliary applications / _h[electronic resource] _cGregory Roos, Murdoch University, Perth, Western Australia.
250			_a2nd ed.
264		1	_aWaltham, MA : _bAcademic Press, _c2014.
264		4	_c�2014
300			_a1 online resource
336			_atext _btxt _2rdacontent
337			_acomputer _bc _2rdamedia
338			_aonline resource _bcr _2rdacarrier
520			_aKey Chiral Auxiliary Applications, Second Edition is a detailed compilation of chiral auxiliary applications organized by type of transformation. Continuing from the most important and relevant auxiliaries described in its predecessor, the three-volume set Compendium of Chiral Auxiliary Applications (2001), as well as advances in the field, the book provides a vital and timely resource for chemists in the field. Each reaction class includes a series of tables and graphical abstracts of real reactions from the literature and patents to enable easy review and comparison of results. This anticipated edition is based on a screening of nearly 40,000 auxiliary reaction applications, with details supplied for the more than 13,000 selected representative entries: synthetic route, reagents, yields, diastereomeric/enantiomeric excesses, and characterization data. Updated and streamlined with more than 60% new material, Key Chiral Auxiliary Applications provides valuable guidance and reliable content for selecting the best auxiliary for a specific asymmetric synthetic transformation. Provides a comprehensive compilation based on nearly 40,000 diverse applications of chiral auxiliaries for selecting the best synthetic route to optically pure compoundsContains over 60% new material with 13,000+ auxiliary applications categorized by reaction type, with reaction details and chemical and optical yields in one unique resource.
505	0		_aFront Cover; Key Chiral Auxiliary Applications; Copyright; CONTENTS; ACKNOWLEDGEMENTS; FOREWORD; PREFACE TO THE 2ND EDITION; ABBREVIATIONS; 1.INTRODUCTION; 1.1. BACKGROUND; 1.2. THE CHIRAL AUXILIARY APPROACH; 1.3. THIS COLLECTION; REFERENCES; 2.ALKYLATION AND RELATED REACTIONS I; 2.1 ALLYL AND BENZYL RELATED CARBANIONS; 2.2 ALLENIC ETHER TANDEM ACYLATION-CYCLIZATION; 2.3 ALDEHYDE DERIVED NUCLEOPHILES; 2.4 KETONE DERIVED NUCLEOPHILES; 2.5 ALDEHYDE AND KETONE ENOLATES WITH AUXILIARY-CONTAINING ELECTROPHILES; REFERENCES; 3.ALKYLATION AND RELATED REACTIONS II.
505	8		_a10.ADDITION TO C=N BONDS10.1 REDUCTION OF IMINES, IMINIUM IONS, HYDRAZONES AND OXIMES; 10.2 NUCLEOPHILIC ADDITION; 10.3 RADICAL ADDITION; 10.4 UGI COUPLING; REFERENCES; 11.ADDITION TO C=O BONDS I; 11.1 REDUCTION; 11.2 WITTIG & RELATED OLEFINATION; 11.3 ADDITION OF ORGANOMETALLIC AND RELATED REAGENTS; REFERENCES; 12.ADDITION TO C=O BONDS II; 12.1 ADDITION OF ENOLATES (ALDOL AND RELATED REACTIONS); REFERENCES; 13.ADDITION TO C=O BONDS III; 13.1 ADDITION OF ENOLATES (ALDOL AND RELATED REACTIONS); 13.2 TANDEM REACTIONS; 13.3 RADICAL REACTIONS; REFERENCES; 14. CYCLOADDITIONS I.
650		0	_aAsymmetric synthesis.
650		0	_aEnantioselective catalysis.
650		0	_aEnantiomers.
650		7	_aAsymmetric synthesis. _2fast _0(OCoLC)fst00819861
650		7	_aEnantiomers. _2fast _0(OCoLC)fst00909487
650		7	_aEnantioselective catalysis. _2fast _0(OCoLC)fst00909493
655		4	_aElectronic books.
856	4	0	_3ScienceDirect _uhttp://www.sciencedirect.com/science/book/9780124170346
999			_c246875 _d246875