000 05516cam a2200565Ii 4500
001 ocn956655956
003 OCoLC
005 20190328114816.0
006 m o d
007 cr cnu---unuuu
008 160815s2016 nyua ob 001 0 eng d
040 _aN$T
_beng
_erda
_epn
_cN$T
_dOPELS
_dEBLCP
_dUIU
_dYDX
_dCCO
_dQCL
_dOCLCQ
_dOCLCO
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019 _a962437953
020 _a9780128019054
_q(electronic bk.)
020 _a0128019050
_q(electronic bk.)
020 _z9780128018941
020 _z0128018941
035 _a(OCoLC)956655956
_z(OCoLC)962437953
050 4 _aQD412.B1
072 7 _aSCI
_x013040
_2bisacsh
082 0 4 _a547/.05/671
_222
100 1 _aGrimes, Russell N.,
_d1935-
_eauthor.
245 1 0 _aCarboranes /
_h[electronic resource]
_cby Russell N. Grimes.
250 _a3rd ed.
264 1 _aNew York :
_bAcademic Press,
_c[2016]
264 4 _c�2016
300 _a1 online resource (xv, 1041 pages) :
_billustrations.
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
490 1 _aOrganometallic chemistry
504 _aIncludes bibliographical references and index.
588 0 _aPrint version record.
520 _aCarboranes, Third Edition, by Russell Grimes, is the definitive resource on the subject. Completely updated with a wealth of research and review articles published in this active field since the previous volume was released in 2011, the book provides a readable and concise introduction to the basic principles underlying the synthesis, structures, and reactions of carboranes, heterocarboranes, and metallacarboranes. Following the valuable foundational information, the book explores the advances in practical applications for the many areas in which experts have discovered that carboranes afford new possibilities for solving problems and advancing the science. These disciplines include polymer science, catalysis, biomedicine, nanomaterials, and others.
505 0 _aFront Cover; Carboranes; Copyright; Dedication; Contents; Preface to the Third Edition; Preface to the Second Edition; Chapter 1: Introduction and History; References; Chapter 2: Structure and Bonding; 2.1. General perspective; 2.2. Nomenclature and numbering; 2.3. The localized-bond approach; 2.4. Structural patterns in boron clusters; 2.5. Extensions of the electron-counting rules; 2.6. Electron-counting in classically bonded clusters; 2.7. Isomer stability and cage rearrangement; 2.8. Cluster aromaticity; 2.9. ``Electron Deficiency�� in Polyhedral Boron Clusters; References.
505 8 _aChapter 3: Synthesis and Reactivity: An Overview3.1. General preparative routes to carboranes; 3.1.1. Borane-Alkyne Gas Phase Reactions; 3.1.2. Borane-Alkyne Reactions in Solution; 3.1.3. Carborane-Alkyne Reactions; 3.1.4. Carbon Insertion Via Cyano- and Isocyanoboranes; 3.1.5. Carboranes from Organoboranes; 3.2. Interconversion reactions; 3.2.1. Polyhedral Rearrangement; 3.2.2. Metal-Promoted Cage Fusion; 3.2.3. Polyhedral Expansion and Contraction; 3.3. Substitution at cage carbon and boron atoms; 3.4. Carboranes as substituents and ligands.
505 8 _aChapter 4: Small Carboranes: Four- to Six-Vertex Clusters4.1. Overview; 4.2. 4-Vertex open clusters; 4.2.1. CB3Hx and C2B2Hx; 4.3. 5-Vertex open clusters; 4.3.1. Nido- and Arachno-CB4 Systems; 4.3.2. Nido-1,2-C2B3H7; 4.3.3. Other Open-Cage C2B3 Clusters; 4.3.4. Nido-C3B2 Clusters; 4.4. 5-Vertex closo clusters; 4.4.1. CB4Hx; 4.4.2. 1,5-C2B3H5; 4.4.2.1. Synthesis; 4.4.2.2. Structure and Bonding; 4.4.2.3. Physical Properties and Reactivity; 4.4.3. Closo-C3B2H5+; 4.5. 6-Vertex open clusters; 4.5.1. Nido-2-CB5H9; 4.5.1.1. Synthesis; 4.5.1.2. Structure and Properties; 4.5.2. Hypho-CB5H13.
505 8 _a4.5.3. Nido-2,3-C2B4H84.5.3.1. Synthesis; 4.5.3.2. Structure and Properties; 4.5.4. Nido-2,4-C2B4H8; 4.5.4.1. Synthesis; 4.5.4.2. Structure and Properties; 4.5.5. Arachno- and Hypho-C2B4Hx Clusters; 4.5.6. Nido-2,3,4-C3B3H7; 4.5.6.1. Synthesis; 4.5.6.2. Structure and Properties; 4.5.7. Nido-2,3,5-C3B3H7; 4.5.7.1. Synthesis; 4.5.7.2. Structure and Properties; 4.5.8. Nido-2,3,4,5-C4B2H6; 4.5.8.1. Synthesis; 4.5.8.2. Structure and Properties; 4.5.9. Nido-2,3,4,5,6-C5BH6+; 4.5.9.1. Synthesis; 4.5.9.2. Structure and Properties; 4.6. 6-Vertex closo clusters; 4.6.1. 1-CB5H7 and 1-CB5H6-
505 8 _a4.6.1.1. Synthesis4.6.1.2. Structure and Properties; 4.6.2. 1,2- and 1,6-C2B4H6; 4.6.2.1. Synthesis; 4.6.2.2. Structure and Physical Properties; 4.6.2.3. Reactions of Closo-1,2-C2B4 Clusters; 4.6.2.4. Reactions of Closo-1,6-C2B4 Clusters: Hydrolysis, Methanolysis, and Oxidation; 4.6.2.5. Polyhedral Expansion; 4.6.2.6. Cage Linkage; 4.6.2.7. Introduction of Substituents; References; Chapter 5: Intermediate Carboranes: Seven- to Nine-Vertex Clusters; 5.1. Overview; 5.2. 7-Vertex open clusters; 5.2.1. Nido-C2B5H8-; 5.3. 7-Vertex closo clusters; 5.3.1. 2-CB6H7-; 5.3.2. 2,3-C2B5H7.
650 0 _aCarboranes.
650 7 _aSCIENCE
_xChemistry
_xOrganic.
_2bisacsh
650 7 _aCarboranes.
_2fast
_0(OCoLC)fst00846954
650 7 _aCarborane
_2gnd
_0(DE-588)4147321-8
650 7 _aCarboranes.
_2ram
650 0 7 _aCarborane.
_2swd
655 4 _aElectronic books.
776 0 8 _iPrint version:
_aGrimes, Russell N., 1935-
_tCarboranes.
_dNew York, Academic Press, 2016
_z9780128018941
830 0 _aOrganometallic chemistry.
856 4 0 _3ScienceDirect
_uhttp://www.sciencedirect.com/science/book/9780128018941
999 _c247399
_d247399